Browsing Department of Chemistry by Author "Hollett, Joshua W."
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Crystal structure and computational study of an oxo-bridged bis-titanium(III) complex
Bloomfield, Hannah R.; Hollett, Joshua W.; Ritch, Jamie S. (International Union of Crystallography, 2021-06)The solid-state structure of the new compound mu-oxido-bis[dichloridotris(tetrahydrofuran-kappa-O)titanium(III)], [Ti2Cl4O(C4H8O)6], at 150 K has been determined. The crystal has monoclinic (C2/c) symmetry and the complex ... -
Effect of the tether length upon Truce‐Smiles rearrangement reactions
Fuss, David; Wu, Yu Qi; Grossi, Michael R.; Hollett, Joshua W.; Wood, Tabitha E. (John Wiley & Sons, Ltd., 2017-07-07)This report examines the effect of substrate design upon the Truce‐Smiles rearrangement, an intramolecular nucleophilic aromatic substitution reaction. The length of the molecular spacer that tethers the carbanion nucleophile ...