Now showing items 1-10 of 14
A new polymorph of phenylselenium trichloride
(International Union of Crystallography, 2019-11)
A second polymorph of phenylselenium trichloride, PhSeCl3 or C6H5Cl3Se, is disclosed, which is comprised of asymmetric chlorine-bridged noncovalent dimer units rather than polymeric chains. These dimers are each weakly ...
Effect of the tether length upon Truce‐Smiles rearrangement reactions
(John Wiley & Sons, Ltd., 2017-07-07)
This report examines the effect of substrate design upon the Truce‐Smiles rearrangement, an intramolecular nucleophilic aromatic substitution reaction. The length of the molecular spacer that tethers the carbanion nucleophile ...
Temperature and freezing effects on phosphorus release from soils to overlying floodwater under flooded-anaerobic conditions
(American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, 2020-03-30)
Increased phosphorus (P) availability under flooded, anaerobic conditions may accelerate P loss from soils to water bodies. Existing knowledge on P release to floodwater from flooded soils is limited to summer conditions ...
Synthesis and coordination chemistry of cyclic seleno- and telluroureas
(De Gruyter, 2018-07)
Chalcogenated derivatives of N-heterocyclic carbene ligands have received increasing attention due to their diverse chemical reactivity and potential applications in fields such as medicine and materials chemistry. ...
Truce–Smiles rearrangement of substituted phenyl ethers
(The Royal Society of Chemistry, 2015-05-26)
The requirement of aryl ring activation by strong-electron withdrawing substituents in substrates for the intramolecular nucleophilic aromatic substitution reaction known as the Truce–Smiles rearrangement was examined. ...
Diverse silver(I) coordination chemistry with cyclic selenourea ligands
(The Royal Society of Chemistry, 2018-01-30)
The coordination chemistry of two selenourea ligands (SeIMes and SeIPr) towards silver(I) triflate and silver(I) nitrate was investigated. Two aggregation modes were observed in the solid state, strongly influenced by the ...
Spectroscopic approaches for studying faint text on a wooden tally from Invincible (1758)
(International Journal of Conservation Science, 2013-01-01)
In this study we describe the application of X-ray fluorescence, variable pressure scanning electron microscopy and visible (420-720 nm) hyperspectral imaging to assess the surface properties of a wood tally stick that was ...
Gypsum Amendment Reduces Redox-Induced Phosphorous Release from Freshly Manured, Flooded Soils to Floodwater
(American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, 2019-01-01)
The effectiveness of gypsum in reducing runoff P losses from soils and the mechanisms responsible are well documented; however, gypsum amendment effects in reducing redox-induced P losses from flooded soils are less ...
Chemistry and the Environment: A Chemistry Perspective for discussion of Environmental Issues
(OpenStax and University of Winnipeg Library, 2020-08-21)
Chemistry and the Environment is designed to accompany a one-semester course in chemistry-based discussions of important environmental issues such as air pollution, the ozone layer, climate change and water quality. Chemical ...
Workbook to accompany Chemistry and the Environment: A Chemistry Perspective for discussion of Environmental Issues
(OpenStax and University of Winnipeg Library, 2020-09-08)