Now showing items 1-3 of 3
The Truce–Smiles rearrangement and related reactions: a review
(NRC Research Press, 2017-01-16)
The Truce–Smiles rearrangement is an X → C aryl migration reaction that is achieved by an intramolecular nucleophilic aromatic substitution pathway. The reaction exhibits a wide substrate scope with respect to a migrating ...
Truce–Smiles rearrangement of substituted phenyl ethers
(The Royal Society of Chemistry, 2015-05-26)
The requirement of aryl ring activation by strong-electron withdrawing substituents in substrates for the intramolecular nucleophilic aromatic substitution reaction known as the Truce–Smiles rearrangement was examined. ...
Effect of the tether length upon Truce‐Smiles rearrangement reactions
(John Wiley & Sons, Ltd., 2017-07-07)
This report examines the effect of substrate design upon the Truce‐Smiles rearrangement, an intramolecular nucleophilic aromatic substitution reaction. The length of the molecular spacer that tethers the carbanion nucleophile ...