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The Truce–Smiles rearrangement and related reactions: a review
(NRC Research Press, 2017-01-16)
The Truce–Smiles rearrangement is an X → C aryl migration reaction that is achieved by an intramolecular nucleophilic aromatic substitution pathway. The reaction exhibits a wide substrate scope with respect to a migrating ...
Effect of the tether length upon Truce‐Smiles rearrangement reactions
(John Wiley & Sons, Ltd., 2017-07-07)
This report examines the effect of substrate design upon the Truce‐Smiles rearrangement, an intramolecular nucleophilic aromatic substitution reaction. The length of the molecular spacer that tethers the carbanion nucleophile ...